$re = '/(\d{2}\.\d{3})([A-Z]{2})/';
$str = '00.000LB
12.345GM
XXXXXXXX
XX.XXXXX
00.000XX
1LB
1.0LB
1.00LB
01.00LB
01.000LB
001.00LB';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php