$re = '/\\\\(\w)*\\\\/m';
$str = 'D:\\pcap\\WebMail
D:\\pcap1\\WebMail\\1\\1
C:\\pcap\\WebMail\\sd\\
D:\\pcapFixed\\WebMail\\AOL\\AOL_Accessible\\20121107\\AOL_lite_ACCESSIBLE_001_Login.xml';
$subst = "\\replacedFolder\\";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php