$re = '/time\s(\w+\s*\{\s\n(\s{2,8}\w+\s\w+\s.+\n){1,2}\})/';
$str = '### ACL de tiempo.
## ¿Son estos los horarios que necesita?
time laboral {
weekly mtwhf 07:15 - 12:29
weekly mtwhf 13:15 - 16:00
}
time almuerzo{
weekly mtwhf 12:30 - 13:14
}
time noche {
weekly mtwhf 15:45 - 23:55
weekly mtwhf 00:01 - 07:14
}
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php