$re = '/^([a-zA-Z]+\w*)[ \t]*=(?!=).+/m';
$str = 'aa = 100
bb=100
s=2
a90=0
a91 =0
a92 = 0
app = Mgr()
app2 = mary()
app3 = mary(x=2)
# below should NOT match
# a = 100
hello there
fred(xx=100)
def mary(xx=100)
77=0
88 = 0
a93 == 0
a94 0
a95 0 =
if __name__ == "__main__":
app.run(host="0.0.0.0", port=8000)
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php