$re = '/Else(?!If)[ \t]*;?/m';
$str = 'Else ;
Else
Else ;//------------------------------------------------------
//ElseIf TPlayer(ob) && TPlayer(ob).ProcessLine(Line)
//ElseIf bc=2
//Else
Else ;//ну вообще большой взрыв
';
$subst = "\} else \{ ";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php