$re = '/^([0-1]\d:[0-5]\d)|(^20:0[0-5])/m';
$str = '00:00
01:00
02:00
03:00
04:00
05:00
06:00
07:00
08:00
09:00
10:00
11:00
12:00
12:09
12:19
12:29
12:30
12:31
12:32
12:33
12:34
12:35 midday (all days of week)
12:36
13:00
14:00
15:00
16:00
17:00
18:00
19:00
19:35 evening (sun-fri)
20:00
20:05 evening (saturday)
20:15
20:25
20:35
21:00
22:00
23:00';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php