$re = '/(?<sol>.*?)\s*(?<isaret>\<\>|\>=|\>|\<=|\<|\=\=|\!\=)\s*(?<sag>.*?)\s*(?<ayrac>&&|\|\|)*(\s|$)/mi';
$str = '1 > 2 && sua== 5 && x >= 9 && v != 25 && b <> 5 && a < 8 && h <= "52"';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php