$re = '/^([a-zA-Z]:(?=\\\\)|\\\\\\\\(?:[^\*:<>?\\\\\/|]+\\\\[^\*:<>?\\\\\/|]+|\?\\\\(?:[a-zA-Z]:(?=\\\\)|(?:UNC\\\\)?[^\*:<>?\\\\\/|]+\\\\[^\*:<>?\\\\\/|]+)))/';
$str = 'C:\\a\\path
\\\\server\\share\\some\\path
\\\\?\\C:\\a\\path
\\\\?\\server\\share\\a\\path
\\\\?\\UNC\\server\\share\\a\\path';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php