$re = '/:(?!:|\s)([^\s|\/]{1,}?)(?=:)/m';
$str = ': :smile:http://baidu.com:9090 :smile1:表情:测试1 :smile: :tv_可爱: :smile: :::::smile:: :tv_doge: ::::tv_doge:: :::tv_doge: : :::: :tv_doge: :::tv_doge::smile:smile:';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php