$re = '/^#\s(\d+)\s+-?(\d{2}):(\d{2})\.(\d{3})\s(\d+)\s(\d{2}:\d{2})$/m';
$str = 'StNr Laptime Lap Tageszeit
# 665 -02:04.137 6 10:52
# 665 -01:47.625 5 10:50
# 665 -01:49.546 4 10:48
# 665 -01:57.014 3 10:47
# 665 -01:51.407 2 10:45
# 665 -00:00.000 1 10:43
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php