$re = '/^\d{2}$/m';
$str = '# All POS codes should be 2 digits
# NOTE: Single digits should have a leading 0
# It\'s possible data loading might drop this! This regex would therefore fail
# This regex will also match codes that are currently unassigned
# - https://www.cms.gov/medicare/coding-billing/place-of-service-codes/code-sets
01
04
10
55
99
# Checks
0A
1
9
A0
--
990
010
**
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php