$re = '/[\/\*A-Z0-9_\s]*(?=\{)\{CAN_SID[A-Z0-9_]+(?=(_([A-Z0-9]{6}[0-9]))).+(?=(CAN_SID[A-Z0-9_]+(?=(_([A-Z0-9]{6}[0-9])))))/m';
$str = '/* UACK */ {CAN_SID_UACK_IDT1S03, CAN_SID_N_UACK_0_IDT1S03}, /* blah blah blah */
{RSTART_';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php