$re = '/(\[@Title]), ([^,)]+)/';
$str = 'IF(SEARCH(LEFT([@Title], 3), "CMO") , "Marketing",
IF(SEARCH(LEFT([@Title], 3), "CIO") , "IT",
IF(SEARCH(LEFT([@Title], 3), "CTO") , "IT",
IF(SEARCH(LEFT([@Title], 3), "CRO") , "Sales",
IF(SEARCH(LEFT([@Title], 3), "CPO") , "Product",
IF(SEARCH(LEFT([@Title], 3), "COO") , "Operations",
IF(SEARCH(LEFT([@Title], 3), "CFO") , "Finance",
IF(SEARCH(LEFT([@Title], 3), "CEO") , "Exective",
IF(SEARCH([@Title], "President") , "Exective",
IF(SEARCH([@Title], "Chairman") , "Exective",
IF(SEARCH([@Title], "Social"), "Social" ,
IF(SEARCH([@Title], "Content"), "Content" ,
IF(SEARCH([@Title], "Blog"), "Blog" ,
IF(SEARCH([@Title], "Digital"), "Digital" , ';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php