$re = '/(?<!\S)(?:(?:[1-9]?\d|1\d\d|2[0-4]\d|25[0-5])\.?\b){4}(?!\S)/';
$str = 'Validating IP V 4
1.1.1.1
2.2.2.2
3.3.3.3
4.4.4.4
5.5.5.5
6.6.6.6
7.7.7.7
8.8.8.8
9.9.9.9
10.10.10.10
A single character of: a, b or c
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php