$re = '/((?:[0-9]{1,3}\.){3}[0-9]{1,3}).*(([0-9A-Fa-f]{2}[:-]){5}([0-9A-Fa-f]{2}))/';
$str = '
IP address HW type Flags HW address Mask Device Ethernet interface VLAN ID
10.26.64.1 0x1 0x2 e0:97:96:bd:e6:48 * veip0.2
1.1.1.2 0x1 0x2 00:26:86:00:00:00 * br0
192.168.1.3 0x1 0x2 b8:27:eb:48:3d:e6 * br0 LAN3 0
IPv6 Neighbor Table:
IPv6 address HW Address Device
fe80::9a97:d1ff:fe70:eeb6 98:97:d1:70:ee:b6 br0
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php