$re = '/^([^,]*,){39}"/m';
$str = ',1414,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"kepware~5~63CC97F2-5494-43F2-9F92-79A2BEF58D2A","5:39265338",,1473800029,"2016-09-13 20:54:20.206 +0000 Tag=""MODBUS.ROBOT.Position_Base"" Value=""1414"" Quality=""good"" ","RS5c
kepware",Kepware,".206","1473800060.206",,,20,13,54,september,20,tuesday,2016,0,,,"24.97.250.66",kepware,1,,,"--_::._+_=""..""_=""""_=""""_",,Kepware,Kepware,RS5c,,,,,,29,0,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"1487.42566",,"kepware~5~63CC97F2-5494-43F2-9F92-79A2BEF58D2A","5:39143140",,1473798904,"2016-09-13 20:35:35.147 +0000 Tag=""OmronCJ.PLC1.Suply_conv.Belt_speed"" Value=""1487.42566"" Quality=""good"" ","RS5c
kepware",Kepware,".147","1473798935.147",,,20,13,35,september,35,tuesday,2016,0,,,"24.97.250.66",kepware,1,,,"--_::._+_=""...""_="".""_=""""_",,Kepware,Kepware,RS5c,,,,,,29,0,,
,,,,,,,,,,,,,,,,,,,,,0,,,,,,,,,,,,,,"kepware~5~63CC97F2-5494-43F2-9F92-79A2BEF58D2A","5:39117933",,1473798672,"2016-09-13 20:31:42.457 +0000 Tag=""MODBUS.ROBOT.Velocity_Sholder"" Value=""0"" Quality=""good"" ","RS5cSplunk1
kepware",Kepware,".457","1473798702.457",,,20,13,31,september,42,tuesday,2016,0,,,"24.97.250.66",kepware,1,,,"--_::._+_=""..""_=""""_=""""_",,Kepware,Kepware,RS5c,,,,,,29,0,,
,,,,,,,,,,,,,,,,,,,,,,,,,"1491.82166",,,,,,,,,,"kepware~5~63CC97F2-5494-43F2-9F92-79A2BEF58D2A","5:39105700",,1473798560,"2016-09-13 20:29:50.387 +0000 Tag=""OmronCJ.PLC1.Assy_conv.belt_speed"" Value=""1491.82166"" Quality=""good"" ","RS5c
kepware",Kepware,".387","1473798590.387",,,20,13,29,september,50,tuesday,2016,0,,,"24.97.250.66",kepware,1,,,"--_::._+_=""...""_="".""_=""""_",,Kepware,Kepware,RS5c,,,,,,29,0,,
,,,,,,,,,,,,,,,,,,,,1605,,,,,,,,,,,,,,,"kepware~5~63CC97F2-5494-43F2-9F92-79A2BEF58D2A","5:39087971",,1473798396,"2016-09-13 20:27:06.649 +0000 Tag=""MODBUS.ROBOT.Velocity_Max_Wrst3"" Value=""1605"" Quality=""good"" ","RS5c
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php