$re = '/(\-((0[0-9]|1[0-2]):00|0[39]:30)|\+((0[0-9]|1[0-4]):00|(0[34569]|10):30|(0[58]|12):45))/m';
$str = '-99:99
-13:00
-12:45
-12:30
-12:15
-09:15
+02:15
+03:44
+03:45
+03:46
+14:15
+14:45
+99:99
-12:00
-11:00
-10:00
-09:30
-09:00
-08:00
-07:00
-06:00
-05:00
-04:00
-03:30
-03:00
-02:00
-01:00
-00:00
+00:00
+01:00
+02:00
+03:00
+03:30
+04:00
+04:30
+05:00
+05:30
+05:45
+06:00
+06:30
+07:00
+08:00
+08:45
+09:00
+09:30
+10:00
+10:30
+11:00
+12:00
+12:45
+13:00
+14:00
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php