$re = '/^(2[0-3]|[01][0-9]):([0-5][0-9]):([0-5][0-9])(\.[0-9]+)?(Z|[+-](?:2[0-3]|[01][0-9]):[0-5][0-9])?$/m';
$str = '09:00:00+07:00';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php